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Otherwise it doesn't make sense at all needing frequent injections

Revealingly, one of the first attempts to get an idea on the midpoint potential of the GSH/GSSG couple back in 1952 made use of enzymatic catalysis (Rall and Lehninger, 1952): The NADPH/NADP did simply not react with the GSH system until a then newly discovered enzyme, glutathione reductase, was added to the reaction mixture

Schnichels, S., Paquet-Durand, F., Loscher, M., Tsai, T., Hurst, J., Joachim, S

These interventions generally promote wound healing

2024;103:e39398

If toxic compounds are ingested in large amount, the glutathione stores are depleted