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doi:10.1016/s1096-6374(00)80011-8
Depending on concentration, transition-metal availability, oxygen tension, and enzymatic context, polyphenols can generate semiquinones, quinones, hydrogen peroxide, or glutathione-consuming intermediates that shift a system from cytoprotection toward oxidative damage ( 3 Interfacial mechanisms of phenolic functionalization on MSNs 3.1 Adsorption and confinement-dominant loading Adsorption-dominant loading is based mainly on non-covalent affinity between phenolics and the pore/surface environment
The spontaneous and enzymatic reaction of N-acetyl-p-benzoquinonimine with glutathione: a stopped-flow kinetic study
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So even if you eat glutathione-rich foods or take supplements, only a small fraction of the amount affects your actual levels
Some perceive this as a mismatch between our ancient genes and modern environment [2]
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